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Mass Spectrometry Quiz

Mass Spectrometry Quiz

Test your knowledge on mass spectrometry and its history

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  • 1.
    What is the base peak in the mass spectrum?

    Your answer:
    Correct answer:

    The base peak is the peak with the greatest intensity among all peaks in the spectrum. The intensity of each peak in the spectrum is expressed as a percentage relative to the intensity of the base peak.

  • 2.
    How many elements of the periodic table have only a single stable isotope?

    Your answer:
    Correct answer:
    These so-called monoisotopic elements are beryllium, fluorine, sodium, aluminum, phosphorus, scandium, vanadium, manganese, cobalt, arsenic, rubidium, yttrium, niobium, rhodium, indium, iodine, cesium, lanthanum, praseodymium, europium, terbium, holmium, thulium, lutecium, rhenium, and gold.
  • 3.
    What is the trajectory of a charged particle moving perpendicularly to a uniform magnetic field in a vacuum?

    Your answer:
    Correct answer:

    The magnetic force is perpendicular to the velocity so that it does no work on the charged particle. The particle’s kinetic energy and speed thus remain constant. The direction of motion is affected but not the speed.

  • 4.
    Who built the first mass spectrometer in Czechia?

    Your answer:
    Correct answer:

    The first mass spectrometer in the country was built in the Laboratory of Physical Chemistry of the Czechoslovak Academy of Sciences. Four young scientists, Vladimír Čermák, Vladimír Hanuš, Čestmír Jech and Josef Cabicar, took part in its construction. At the time of the post-war shortage, it was very difficult to find the necessary components; some parts originated from captured German military equipment. The mass spectrometer was of the Nier type with simple focusing and 60° magnetic field, pumped by a mercury diffusion pump. The device was completed after two years, in 1953. The construction of this instrument was an extraordinary achievement awarded a year later by the State Prize. [Z. Herman, Chem. Listy 104, 955, 2010]

  • 5.
    Lunar craters are usually named after scientists and explorers. One of the craters on the Moon is named after a prominent scientist in the field of mass spectrometry. Who is named after?

    Your answer:
    Correct answer:

    Aston is a 44-kilometer lunar impact crater located along the northwestern limb of the Moon. The crater was named in honor of Francis W. Aston.

  • 6.
    Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. Who discovered it?

    Your answer:
    Correct answer:

    Chemical ionization was discovered in the laboratories of the Humble Oil and Refining Company in Baytown, TX. Munson and Field’s seminal paper on chemical ionization was published in 1966.  [https://doi.org/10.1021/ja00964a001]

  • 7.
    What was the largest number of quadrupoles connected in series for tandem mass spectrometry in a commercial instrument?

    Your answer:
    Correct answer:
    A penta-quadrupole mass spectrometer contains three quadrupole filters and two rf-only quadrupole collision cells. It allows MS3 experiments.  Extrel once offered such a spectrometer.
  • 8.
    What is the trajectory of a charged particle moving parallel to a uniform electric field in a vacuum?

    Your answer:
    Correct answer:

    If a positive charge is moving in the same direction as the electric field vector the particle's velocity will increase. If it is moving in the opposite direction it will decelerate. If a negative charge is moving in the same direction as the electric field vector the particle will decelerate. If it is moving in the opposite direction it will accelerate.

  • 9.
    Which mass spectrometer was carried by the American spacecraft Viking 1 sent to the planet Mars in 1975?

    Your answer:
    Correct answer:
    Viking 1 carried two mass spectrometers, both equipped with double-focusing analyzers and electron ionization sources. The first spectrometer with a Mattauch-Herzog geometry was designed by Alfred Nier; it was intended to analyze the upper atmosphere of Mars. The second one with a Nier- Johnson geometry was part of the GC/MS apparatus designed by Klaus Biemann. It was used to analyze the regolith and the atmosphere at the landing site.
  • 10.
    What is the electric charge of an ion with m/z = m?

    Your answer:
    Correct answer:

    The particle carries one elementary charge, the value of which is 1.602 176 634 × 10−19 C (exactly).

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